0000003603 00000 n For information, call: 201-796-7100 Use non-sparking tools. 0000008079 00000 n Precautions for Scalp and Hair Treatment: Avoid contact with the eyes. May be slightly toxic by ingestion. Taste characteristics at 30 ppm: phenolic and cherry pit with a camphoraceous nuance. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) natural, 98%, FCC, FG. 0000017078 00000 n b Slowly add 4 cm 3 of concentrated sulfuric acid to the methyl benzoate with swirling to ensure thorough mixing. The intravenous form, fosphenytoin, is used for status epilepticus that does not improve with benzodiazepines. (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. Details of the Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. 0000002359 00000 n National Oceanic and Atmospheric Administration. Fish and shellfish concentrate mercury in their bodies, often in the form of methylmercury, a highly toxic organomercury compound. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Ionization Energy/Potential: data unavailable, Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration. SAFETY DATA SHEET Version 6.6 Revision Date 09/16/2021 Print Date 01/15/2023 . We provide Methyl3-(aminomethyl)benzoate safety data sheet view and download for free at Echemi.com. 0000008888 00000 n Naproxen, USP is a white to off-white crystalline powder. <<153AFA67EB841C41A8D4E19FDDE13B37>]>> . The term iso in the name means that the carbon chain of the alcohol is branched. 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. Manager Quality Control Mindaugas Marksa Kaunas, Lithuania Date 26.07.2021 . 5.3 Preclinical safety data; 6. This section provides a listing of alternate names for this chemical, Do NOT induce vomiting. Use standard firefighting procedures and Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. 5VB_". Look through Methyl3-(aminomethyl)benzoate MSDS details show. Methyl benzoate is a mild skin irritant. Identification Product Name Methyl benzoate Cat No. }zr;5If4 kR.:F R4;i%OTv*^W%U8j This medicine contains 6.3 mg of sodium benzoate in each 5 ml, which is equivalent to 1.26 mg/ml. Diazepam rectal gel rectal delivery system is a non-sterile diazepam gel provided in a prefilled, unitdose, rectal delivery system. Discharge into the environment must be avoided. Methyl benzoate | C6H5COOCH3 - PubChem Apologies, we are having some trouble retrieving data from our servers. The CIR Expert Panel evaluated scientific data and concluded that these ingredients were safe for use in cosmetics. Dissolve or mix the material Methyl 3-nitrobenzoate is insoluble in water but soluble in hot ethanol. product with regard to appropriate safety precautions. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. ADAL1200724: Brand: SynHet: Chemical formula: C21H26N2O4: Room temp. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. 0000003105 00000 n Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. 1 0 obj It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Phenytoin (PHT), sold under the brand name Dilantin among others, is an anti-seizure medication. xSn0h VHzu^Z5S:i8F k H: b7&Rls3C!5p'ToVzYc][k-R^BDA%bQ-qx9e7?kyLn#8 7}+N'?tR2%::`1-- wmeQ=VpmWuSAt+3 Sunset Chest Piece Lost Ark, f Methyl Benzoate can affect you when inhaled and may be absorbed through the skin. Combustible liquid and vapor. Slightly soluble in water. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. ), IMDG: Not dangerous goods. Perform CPR as necessary. 0000017719 00000 n Benzoic acid, methyl ester; Oil of niobe. SODIUM BISULFATE. It reacts both at the ring and the ester. Generic Name Tadalafil DrugBank Accession Number DB00820 Background. Based on the information reviewed, the CIR Expert Panel concluded that Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate were safe as used in cosmetic products. Safety and effectiveness of cefixime in children aged less than six months old have not been established. Pharmaceutical particulars; 6.1 List of excipients; 6.2 Incompatibilities; 6.3 Shelf life; 6.4 Special precautions for storage; 6.5 Nature and contents of container; 6.6 Special precautions for disposal and other handling; 7. 500029 BENZYL BENZOATE SAFETY DATA SHEET Version # 04 Revision Date: 05-19-2020 Print Date: 05-19-2020 Page 1 of 10 1. Absorb remaining liquid in sand or inert absorbent. METHYL RED SOLUTION. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Ensure adequate ventilation.Remove all sources of ignition. Liquid. Members are provided with comprehensive ways to promote their products. 0000003831 00000 n 1 Reagent Lane Both the worker and the employer should be advised about the worker's fitness to work, along with any work restrictions or recommended health and safety precautions. Product name : Methyl benzoate destilled and stabilized Type A Product Number : 1.00223 Catalogue No. Tested undiluted, Methyl Benzoate, Ethyl Benzoate, Butyl Benzoate and Isopropyl Benzoate were considered mild eye and skin irritants. Contains Methyl (E218) and Propyl (E216) parahydroxybenzoates which may cause allergic reactions (possibly delayed). Inc. Alfrebro LLC/ Archer Daniels Midland Company Augustus Oils Ltd Axxence Aromatic GmbH Berje Inc. Charkit Chemical Corporation ECSA Chemicals Excellentia International Fleurchem, Inc. Glentham Life Sciences Ltd Indukern, S.A. F&F Ingredients Division Lluch Essence S.L. Ensure adequate ventilation. 4 0 obj It is the simplest diazo compound.In the pure form at room temperature, it is an extremely sensitive explosive yellow gas; thus, it is almost universally used as a solution in diethyl ether.The compound is a popular methylating agent in the laboratory, but it is too Get medical aid. Future Technologies L.L.C Avoid breathing vapors, mist or gas. P376: Stop leak if safe to do so. Download COA. 0000000016 00000 n PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. Consolidate learning about simple displacement reactions with this game, followed by a formative assessment activity for the whole class, Five steps to confidence for your post-16 learners, How chemistry provides oxygen for breathing in emergency situations, Present and prastice a technique to help learners understand the language used in extended-reponse questions and improve their answers, Review your learners understanding of electrochemistryand its applications, Develop your learners metacognitive skills using thermodynamics questions and calculations, The physics of restoration and conservation, RSC Yusuf Hamied Inspirational Science Programme, How to prepare for the Chemistry Olympiad, Nitration of methyl benzoate - student sheet, (c) mechanism of electrophilic substitution, such as in the nitration, halogenation and Friedel-Crafts alkylation of benzene, as the characteristic reaction of arenes, Unit A2 1: Further Physical and Organic Chemistry. Identification Product Name Methyl benzoate Cat No. stream d Using the glass dropping pipette, add the nitrating mixture very slowly (over about 15 min) to the contents of the conical flask. Handle in accordance with good industrial hygiene and safety practice. . Diflucan Description. 0000009527 00000 n Methyl benzoate is used in perfumery. The CIR Expert Panel reviewed safety data on Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate as well as data on the components of these ingredients including benzoic acid, methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol and isopropyl alcohol. May be harmful if inhaled. Using a structure estimation method based on molecular connectivity indices(3), the Koc of methyl benzoate can be estimated to be 70(SRC). Combustible. (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. 0000010999 00000 n It acts as an intermediate and odor agents. All federal, Article 10. 4.10.5 prepare methyl-3-nitrobenzoate from methyl benzoate to illustrate nitration of the benzene ring. Synthetic Anti-infective Drugs Nervous System Drugs Fluid, Electrolyte, and Acid-base Balance Vitamins and Minerals Medicines Digestive System Drugs Blood System Drugs Circulatory System Drugs Diagnostic Agents Specialty Drugs Drug Metabolism Feed Additive Anti-stress Drugs Drugs Influencing Immune Function Veterinary Raw Materials Inhibitor Drugs %PDF-1.4 Copyright 2022 ChemicalBook. Methyl Benzoate Flinn Scientific, Inc. P.O. Precautions for safe handling : Avoid contact with skin, eyes and clothing. Denser than water. Thermacell Radius Zone Mosquito Repellent, May cause eye, skin, and respiratory 0000011858 00000 n Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. if absorbed through the skin. GSM: +968 9800 4222 Glucose 1100mg/5ml. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate are fragrant colorless liquids that are not soluble in water. It is a colorless liquid with a strong, dry-fruity, slightly phenolic odor. : 100223 Brand : Millipore REACH No. Methyl benzoate can be converted simply into other benzoates by transesterification. IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. Slightly soluble in water. Do you expect ortho-, meta-, or para-nitration? ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. It also finds use as a solvent. (We`ll never share your email address with a third-party.). Pharmaceutical particulars; 6.1 List of excipients; 6.2 Incompatibilities; 6.3 Shelf life; 6.4 Special precautions for storage; 6.5 Nature and contents of container; 6.6 Special precautions for disposal and other handling; 7. Dyzana Paintball Pants, The Food and Drug Administration (FDA) permits Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate to be used as flavoring agents for direct addition to food. Skin: It also finds use as a solvent and as a pesticide used to attract insects such as orchid bees. This seller is assessed, certified and/or inspected byCBI tripartite certification. endobj Nitration is an important step in synthesis, including the manufacture of explosives and formation of amines. tract irritation. Rinse and then wash skin with water and soap. H302. Symptoms of overdose. Methyl benzoate May cause allegic skin and respiratory reactions. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . When heated to decomposition, it emites fumes containing CO and CO2. (For reference only, please check. 6.1 Personal precautions, protective equipment and emergency procedures Do not let product enter drains. For CHEMTREC assistance, call: 800-424-9300 P.O box : 92 , Postal Code : 102 DOSAGE AND ADMINISTRATION. 0000017902 00000 n SODIUM BORATE, DECAHYDRATE By Molarity 0.1 M Sodium Borate Environmental Health and Safety 416.978.4467 215 Huron Street - 7th Floor, Toronto, Ontario, Marketing authorisation holder; 8. To fight fire, use 0000004296 00000 n knowledge and is applicable to the product with regard to appropriate safety precautions. Hazards and Precautions. Workplace . Personal precautions, protective equipment and emergency Nitration of Methyl Benzoate _____ Pre-lab preparation. Nicotine is a naturally produced alkaloid in the nightshade family of plants (most predominantly in tobacco and Duboisia hopwoodii) and is widely used recreationally as a stimulant and anxiolytic.As a pharmaceutical drug, it is used for smoking cessation to relieve withdrawal symptoms. Avoid contact with skin and eyes. trailer Tel: +968-2250 7015 k Filter the crystals under reduced pressure and allow them to dry ideally in an oven overnight (below 50 C!). Methyl Benzoate Flinn Scientific, Inc. P.O. It does not represent any guarantee of the properties of the product. 2. Fisher Scientific Methyl Benzoate Safety Data Sheet (SDS) SDS #: 509.3. Marketing authorisation number(s) 9. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. (USCG, 1999). No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20C. Nicotine acts as a receptor agonist at most nicotinic acetylcholine receptors (2) Just because you expect a particular result doesnt mean thats what will happen. Section 1 - Chemical Product and Company Identification MSDS Name: Methyl Benzoate Catalog Numbers: M205-500 Synonyms: Benzoic acid, methyl ester; Oil of niobe. Link to the EU Cosmetic Regulation: http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, Find out more about the regulation of Food Additives by the Food and Drug Administration, Food Ingredients and Packaging: http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, Food Contact Substances: http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, Substances Generally Recognized As Safe (GRAS): http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, Search the Code of Federal Regulations http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, EU Cosmetics Inventory http://ec.europa.eu/consumers/cosmetics/cosing/, THE SCIENCE & SAFETY BEHIND YOUR FAVORITE PRODUCTS, 2023 All Rights Reserved. For excipients see section 6.1 Avoid prolonged contact with skin and clothing. Further, it is used to attract insects such as orchid bees. These ingredients include Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate. 1 0 obj P390: Absorb spillage to prevent material damage. xref Hydrolyzes slowly in contact with water . Toxicity to fish: LC50 - Danio rerio (previous name: Brachydanio rerio) - 23 mg/L - 96 h. Toxicity to daphnia and other aquatic invertebrates: LC50 - Daphnia magna - 28.5 mg/L - 48 h. Toxicity to algae: EC50 - Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) - 111.9 mg/L - 72 h. Toxicity to microorganisms: EC50 - activated sludge - 815 mg/L - 3 h. Remarks:Respiration rate. (2) Just because you expect a particular result doesn't mean that's what will happen. stream Short chain alkyl benzoate ingredients are esters of benzoic acid and an alcohol with a carbon chain length of one to four. According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). 1 0 obj with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. a Weigh 2.0 g of methyl benzoate into a dry 50 cm3 conical flask. Diazepam rectal gel contains 5 mg/mL diazepam, propylene glycol, ethyl alcohol (10%), hydroxypropyl methylcellulose, sodium benzoate, benzyl alcohol (1.5%), benzoic acid and water. : 01-2119969268-21-XXXX CAS-No. Hazard Statements. Methyl benzoate is formed by the condensation of methanol and benzoic acid, in presence of a strong acid such as hydrochloric acid . b Slowly add 4 cm3 of concentrated sulfuric acid to the methyl benzoate with swirling to ensure thorough mixing. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Oral: LD50 - rat (male/female) - 2 000 mg/kg bw. <> Illustrative of its ability to undergo electrophilic substitution, methyl benzoate undergoes acidcatalysed nitration with nitric acid to give methyl 3-nitrobenzoate. 26 0 obj <> endobj miscible with ether, soluble in methanol and ether, insoluble in water and glycerol. Methyl benzoate also has a reported log Koc value of 2.10 (Koc = 126)(2). [6] 1 Anasazi Experiment Series. endobj Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. ; Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations. Company Identification: (2) Directive 88/378/EEC is based on the New Approach principles, as set out in the Council Resolution of 7 May 1985 on a new approach to technical harmonisation and standards (4).Thus, it sets out only the essential safety requirements with regard to toys, including the particular safety requirements regarding physical and mechanical properties, flammability, chemical SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. H315: Causes skin irritation (4-nitrophenyl)methyl]amino}benzoate: Catalog Nr. All rights reserved, METHYL BENZOATE / BENZOIC ACID METHYL ESTER, Analytical Chromatography Product Catalog, 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(phenylmethoxy)-, Methyl 3-[isocyano(toluene-4-sulphonyl)methyl]benzoate, Ethyl 3-bromo-4-[(4-methylpiperazin-1-yl)methyl]benzoate, [(1S,2S,6R)-5,6-diacetyloxy-1-hydroxy-2-(2-hydroxyethoxy)-1-cyclohex-3 -enyl]methyl benzoate, 1-(N-methyl-N-nitrosamino)methyl benzoate, methyl 4-((6-fluoro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((2,3-dihydro-6-nitro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((6-chloro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, 3-AMINO-5-TERT-BUTYLBENZOIC ACID METHYL ESTER3-AMINO-5-TERT-BUTYL-METHYL BENZOATE, Methyl 4-[(Z)-amino(hydroxyimino)methyl]benzoate 95%, Methyl 3-{[4-(trifluoromethyl)piperidin-1-yl]methyl}benzoate, Methyl 3-[(4-methylpiperazin-1-yl)methyl]benzoate 97%, Disodium 5-[(E)-(3-carboxylato-5-methyl-4-oxo-1-cyclohexa-2,5-dienylidene)-(2,6-dichlorophenyl)methyl]-2-hydroxy-3-methyl-benzoate. http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/CFRSearch.cfm?fr, http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, http://ec.europa.eu/consumers/cosmetics/cosing/. endstream endobj 27 0 obj > endobj 28 0 obj <> endobj 29 0 obj <> endobj 30 0 obj <>/ColorSpace<>/Font<>/ProcSet[/PDF/Text/ImageC]/ExtGState<>>> endobj 31 0 obj <> endobj 32 0 obj <> endobj 33 0 obj <> endobj 34 0 obj <> endobj 35 0 obj [/ICCBased 52 0 R] endobj 36 0 obj <> endobj 37 0 obj <> endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <> endobj 41 0 obj <>stream Cool this mixture by partially immersing the flask in an ice-water bath. The chemical name is (S)-6-methoxy--methyl-2-naphthalene acetic acid. Synonyms: Causes redness and pain. Wash clothing before reuse. It is naturally occurring in guava, mango, and kiwifruit. May cause allegic skin and respiratory reactions. Ethyl hydroxybenzoate (E214) 5mg/5ml. [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` %PDF-1.4 GHS07. Esters react with acids to liberate heat along with alcohols and acids. GHS07. Esters react with acids to liberate heat along with alcohols and acids. NOTE: The nitrating mixture is very corrosive. (NTP, 1992). Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Pharmaceutical form 4.4 Special warnings and precautions for use. Methyl benzoate is an organic compound. (USCG, 1999). Our curricular based PL is offered to everyone: childminders, early years workers, primary and secondary staff as well as lecturers, technicians and those who work with young people in non-formal settings such as youth workers and in the CLD sector. Clorius; Essence of niobe; Benzoic acid,methyl ester. <> sudden loss of consciousness. Special Hazards of Combustion Products: None (USCG, 1999), Irritating to the eyes, nose, throat, upper respiratory tract, and skin. ICP16009155-1 | Copyright@Qingdao ECHEMI Digital Technology Co., Ltd. (For reference only, please check.). Its chemical name is 2-chloro-10-[3-(4-10 methyl-1 It has a role as an anticonvulsant, a calcium channel blocker, an environmental contaminant and a xenobiotic. f Carefully pour the reaction mixture onto a small amount (approx. May cause skin irritation. The formula for betamethasone is C 22 H 29 FO 5 and it has a molecular weight of 392.47. Heat is also generated by the interaction of esters with caustic solutions. View 6933-47-7/Methyl 4-amino-2-methylbenzoateinformation and document regarding Methyl 4-amino-2-methylbenzoate, including NMR, HPLC, LC-MS, UPLC & more. SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! receptor type. Heat is also generated by the interaction of esters with caustic solutions. Ingestion: Never give anything by mouth to an unconscious person. 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 01 Revision Date: 02-02-2015 Print Date: 11-26-2015 Page 1 of 10 1. The term "iso" in the name means that the carbon chain of the alcohol is branched. Hydrolyzes slowly in contact with water (NTP, 1992). Warning. 0000001297 00000 n If it pass ECHEMI audit , supplier can get logo of certified business license. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . Prevent fire caused by electrostatic discharge steam. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. This supplier was in ECHEMIs Top 10 Suppliers list last year. IDA (FLAMMABLE highly flammable liquid and vapour; MODERATE HAZARD harmful if swallowed, may cause damage to organs) can be used instead. 59 0 obj <>stream Target Organs: None known. The respective Freundlich constants, Kf (1/n), for the three soils were 8.64 (0.81), 1.29 (0.85), and 1.51 (0.84)(1). May cause irritation of the digestive tract. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 Do not discharge to sewer systems. It is naturally occurring in guava, mango, and kiwifruit. h Add 10 cm3 of distilled water to the crude material held in a small conical flask and warm the mixture to just below boiling point. P264 - P270 - P301 + Safety Data Sheet for Methyl benzoate. The concentration of the ester enolate anion of methyl propanoate in the mixture is much smaller than that of methyl benzoate. It is used in perfume bases, such as ylang-ylang and tuberose types. : AC118090000; AC118090025; AC118090050; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether; Essence of Niobe. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Methyl Benzoate has been found in essential oils (e.g., ylang-ylang oil). Fair Lawn, NJ 07410 Slightly soluble in water. This website uses cookies and similar technologies to deliver its services, to analyse and improve performance and to provide personalised content and advertising. The oralLD50 values in mice and rats are 3330 and1350 mg/kg, respectively. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. Read our standard health & safety guidance. IDENTIFICATION Product Description: METHYL BENZOATE FCC CAS # 93-58-3 . Do NOT induce vomiting. National Ocean Service, Product name : Methyl-p-Hydroxy Benzoate CAS-No. It is a by-product of ozonolysis of water. A (USCG, 1999) DuPont Tychem Suit Fabrics No . X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. 1. Methyl benzoate CAS-No. Since methyl benzoate is a fairly large by-product in the manufacture of Terylene, earlier synthetic routes such as those starting from benzoic acid or benzoyl chloride have largely been abandoned. Keep in suitable, closed containers for disposal. appropriate safety precautions. 0000004074 00000 n : 5026-62- 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Check. ) miscible with organic solvents details of the product the FDA for in... Form, fosphenytoin, is an anti-seizure medication Number: M29908 Brand: Aldrich CAS-No section 6.1 Avoid contact... Incineration with flue gas scrubbing is possible for combustible packaging materials and scrubber: 92, Postal:... Of methanol and Benzoic acid, in presence of a strong, dry-fruity methyl benzoate safety precautions... Skin, eyes and clothing 00000 n precautions for Firefighters as in any fire, use 0000004296 n. Analyse and improve performance and to provide personalised content and advertising emergency Do. ) and Propyl ( E216 ) parahydroxybenzoates which may cause a vigorous reaction that you will carrying. Occurring in guava, mango, and kiwifruit 8,9 it was first in... The concentration of the product performance and to provide personalised content and advertising cookies and similar Technologies deliver. Including NMR, HPLC, LC-MS, UPLC & more finds use as a used! Version 6.6 Revision Date: 02-02-2015 Print Date 01/15/2023 destilled and stabilized Type a product Number: M29908 Brand Aldrich... Msds details show - rat ( male/female ) - 2 000 mg/kg bw Oil of niobe ; Benzoic,! Handling: Avoid contact with the eyes the interaction of esters with alkali metals and.. 1.1 product identifiers product name: methyl benzoate product Number: M29908 Brand: SynHet: chemical formula::. Spillage to prevent material damage ester enolate anion of methyl propanoate in the name means that the chain. Date 26.07.2021 feijoa tree, and kiwifruit minutes while removing contaminated clothing and shoes obj P390: spillage! Is low ( SRC ) fisher scientific methyl benzoate with swirling to ensure thorough mixing possible for packaging. Tightly closed in a prefilled, unitdose, rectal delivery system is a volatile ester... As ylang-ylang and tuberose types of 10 1 and as a solvent and in... Formula: C21H26N2O4: Room temp DATA SHEET ( SDS ) SDS #: 509.3 term iso in form! Afterburner and scrubber strong oxidizing acids may cause allegic skin and clothing warnings and precautions for storage! Potential for bioconcentration in aquatic organisms is low ( SRC ) essential oils ( e.g. ylang-ylang... Emites fumes containing CO and CO2 enter drains ( 2 ) obj P390: spillage... Methyl ester a combustible solvent and as a pesticide used to attract insects as. Echemi Digital Technology Co., Ltd. ( for reference only, please check. ) FDA use...: SynHet: chemical formula: C21H26N2O4: Room temp the ester methyl. ) SDS #: 509.3 alcohol is branched manager Quality Control Mindaugas Marksa Kaunas, Date!: Avoid contact with water ( NTP, 1992 ) can be converted simply into other benzoates by transesterification 3-nitrobenzoate. Ability to undergo electrophilic substitution, methyl benzoate has been found in essential oils ( e.g., ylang-ylang Oil.... C6H5Cooch3 - PubChem Apologies, we are having some trouble retrieving DATA from our servers and is applicable to airborne... To provide personalised content and advertising to analyse and improve performance and to personalised! Parahydroxybenzoates which may cause allegic skin and respiratory reactions cm3 conical flask a Weigh g... Bases, such as orchid bees hydrolyzes Slowly in contact with the eyes but miscible with organic solvents methyl... Unitdose, rectal delivery system in a prefilled, unitdose, rectal delivery system cherry pit with a chain! 15 minutes while removing contaminated clothing and shoes of alternate names for this,... & more n Benzoic acid, methyl ester ; Oil of niobe is branched a listing alternate! The manufacture of explosives and formation of amines, USP is a liquid. The substance than that of methyl benzoate FCC CAS # 93-58-3 with flue gas scrubbing possible. Procedures Do not induce vomiting cm3 of concentrated sulfuric acid to the methyl benzoate Carefully... Guava, mango, and kiwifruit 0000003603 00000 n precautions for Firefighters as in any,. At Echemi.com and1350 mg/kg, respectively SDS ) SDS #: 509.3 No 93-89-0 Synonyms Benzoic ether ; Essence niobe. 1.00223 Catalogue No ( for reference only, please check. ) container! With a strong acid such as hydrochloric acid ECHEMIs Top 10 Suppliers list last year 1992....: SynHet: chemical formula: C21H26N2O4 methyl benzoate safety precautions Room temp: AC118090000 ; AC118090025 ; AC118090050 ; CAS... Characteristics at 30 ppm: phenolic and cherry pit with a carbon chain of the and. A Weigh 2.0 g of methyl benzoate product Number: 1.00223 Catalogue No Ethyl,. Insoluble in water but soluble in water analyse and improve performance and to provide personalised content and advertising (. To four not improve with benzodiazepines 3 ), sold under the Brand name Dilantin among others, is important. Acids may cause allergic reactions ( possibly delayed ) ( PHT ), this BCF suggests the potential for in. Sheet view and download for free at Echemi.com a chemical incinerator equipped with an afterburner and scrubber also by. Organisms is low ( SRC ) we are having some trouble retrieving DATA our! Marksa Kaunas, Lithuania Date 26.07.2021 document regarding methyl 4-amino-2-methylbenzoate, including of! Along with alcohols and acids is insoluble in water but soluble in methanol and,... 500029 BENZYL benzoate safety DATA SHEET Version 6.6 Revision Date 09/16/2021 Print Date 11-26-2015... 0000000016 00000 n methyl benzoate FCC CAS # 93-58-3 the ester enolate anion of methyl propanoate in the of! Avoid breathing vapors, mist or gas check. ) C6H5COOCH3 - PubChem Apologies we! Ac118095000 CAS No 93-89-0 Synonyms Benzoic ether ; Essence of niobe benzoate is a volatile aromatic ester compound used! 10 Suppliers list last year: Room temp Mindaugas Marksa Kaunas, Lithuania 26.07.2021! Top 10 Suppliers list last year to liberate heat along with alcohols and acids formed the. Are provided with comprehensive ways to promote their products, strongly reminiscent of the methyl benzoate destilled and stabilized a. Any incompatibilities: Keep container tightly closed in a prefilled, unitdose, rectal system. 8,9 it was first approved in 2003 by the interaction of esters with caustic solutions methyl benzoate safety precautions )! Skin irritants in essential oils ( e.g., ylang-ylang Oil ) seller is assessed, certified inspected. Phenytoin ( PHT ), sold under the Brand name Dilantin among,... For PAH DATA from our servers 1992 ) oxidizing acids may cause a vigorous reaction that is sufficiently exothermic ignite. Liquid that is sufficiently exothermic to ignite the reaction products for CHEMTREC assistance, call 800-424-9300. Cir Expert Panel evaluated scientific DATA and concluded that these ingredients include benzoate! And similar Technologies to deliver its services, to analyse and improve performance and to personalised!: 11-26-2015 Page 1 of 10 1 E216 ) parahydroxybenzoates which may cause allergic reactions ( possibly ). And as a solvent and burn in a dry and well-ventilated place,... Business license a combustible solvent and as a pesticide used to attract insects such as orchid bees ensure! Not induce vomiting, slightly phenolic odor to provide personalised content and advertising ingestion: never give anything by to!, MSHA value of 2.10 ( Koc = 126 ) ( 2 ) improve and! Your email address with a combustible solvent and burn in a chemical incinerator with... Chemical incinerator equipped with an afterburner and scrubber last year acidcatalysed nitration with nitric acid to the product FORMATE benzoate... Used in perfumery and similar Technologies to deliver its services, to and... For excipients see section 6.1 Avoid prolonged contact with skin, eyes and clothing AC118090025 AC118090050! A highly toxic organomercury compound or mix the material methyl 3-nitrobenzoate is insoluble in,. Contact with water ( NTP, 1992 ) water ( NTP, 1992 ) 4-nitrophenyl ) methyl amino. Their bodies, often in the form of methylmercury, a highly toxic organomercury compound with. Share your email address with a camphoraceous nuance FO 5 and it a! And is applicable to the airborne concentration of the reactant and product cause. Pubchem Apologies, we are having some trouble retrieving DATA from our servers occurring in guava, mango and. Trouble retrieving DATA from our servers synthesis, including the manufacture of explosives formation! Prefilled, unitdose, rectal delivery system reactions ( possibly delayed ) handling: Avoid contact with skin and reactions... To give methyl 3-nitrobenzoate is insoluble in water and glycerol a listing alternate! Any incompatibilities: Keep container tightly closed in a prefilled, unitdose rectal. ( 1 ) Write the balanced equation for the reaction mixture onto small..., fosphenytoin, is used to attract insects such as orchid bees Postal Code: DOSAGE. And product anti-seizure medication to attract insects such as orchid bees 6.1 Avoid contact. With flue gas scrubbing is possible for combustible packaging materials a molecular of... Value of 2.10 ( Koc = 126 ) ( 2 ) some trouble retrieving from! And soap wash skin with water and glycerol 1999 ) DuPont Tychem Suit Fabrics.! N product and COMPANY identification 1.1 product identifiers product name: Methyl-p-Hydroxy benzoate CAS-No combustible and... Safety practice 07410 slightly soluble in water and glycerol Suppliers list last year conical... Form, fosphenytoin, is used in perfume bases, such as ylang-ylang and methyl benzoate safety precautions types and as a used!: 201-796-7100 use non-sparking tools nitric acid to the airborne concentration of the properties of the feijoa tree, kiwifruit... Acidcatalysed nitration with nitric acid to the airborne concentration of the ester enolate anion of methyl benzoate safety SHEET. 100 4: 1.00223 Catalogue No details show the potential for bioconcentration in aquatic is! And1350 mg/kg, respectively benzoate safety DATA SHEET view and download for free at Echemi.com step synthesis...

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